Search results for "Magnetic ionic liquid"

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Introducing a new and rapid microextraction approach based on magnetic ionic liquids: Stir bar dispersive liquid microextraction

2017

With the aim of contributing to the development and improvement of microextraction techniques, a novel approach combining the principles and advantages of stir bar sorptive extraction (SBSE) and dispersive liquid-liquid microextraction (DLLME) is presented. This new approach, termed stir bar dispersive liquid microextraction (SBDLME), involves the addition of a magnetic ionic liquid (MIL) and a neodymium-core magnetic stir bar into the sample allowing the MIL coat the stir bar due to physical forces (i.e., magnetism). As long as the stirring rate is maintained at low speed, the MIL resists rotational (centrifugal) forces and remains on the stir bar surface in a manner closely resembling SBS…

Detection limitMagnetic ionic liquidChromatographyChemistryMagnetism010401 analytical chemistryExtraction (chemistry)Analytical chemistryThermal desorption02 engineering and technologyRepeatability021001 nanoscience & nanotechnology01 natural sciencesBiochemistry0104 chemical sciencesAnalytical Chemistrychemistry.chemical_compoundIonic liquidEnvironmental Chemistry0210 nano-technologySpectroscopyBar (unit)Analytica Chimica Acta
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Trace determination of volatile polycyclic aromatic hydrocarbons in natural waters by magnetic ionic liquid-based stir bar dispersive liquid microext…

2017

In this work, a novel hybrid approach called stir bar dispersive liquid microextraction (SBDLME) that combines the advantages of stir bar sorptive extraction (SBSE) and dispersive liquid-liquid microextraction (DLLME) has been employed for the accurate and sensitive determination of ten polycyclic aromatic hydrocarbons (PAHs) in natural water samples. The extraction is carried out using a neodymium stir bar magnetically coated with a magnetic ionic liquid (MIL) as extraction device, in such a way that the MIL is dispersed into the solution at high stirring rates. Once the stirring is ceased, the MIL is magnetically retrieved onto the stir bar, and subsequently subjected to thermal desorptio…

Detection limitMagnetic ionic liquidChromatographyTrace AmountsChemistry010401 analytical chemistryExtraction (chemistry)Analytical chemistryThermal desorption02 engineering and technology021001 nanoscience & nanotechnologyMass spectrometry01 natural sciences0104 chemical sciencesAnalytical ChemistryTap waterIonic strength0210 nano-technologyTalanta
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